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21.
Yanqing Zhao Yingli Su Wangcai Zou Gang Chen Yiqing Deng Jun Cheng Haisheng Ren Qiang Zhao 《应用聚合物科学杂志》2021,138(38):50971
In order to prepare waterborne polyurethane with excellent water resistance and thermodynamic properties, a series of side chain fluorinated waterborne polyurethane-urea (FWPU-UA) was synthesized with polytetramethylene ether glycol, N-(2-methyl-1,3-propanediol-2′-)-perfluoro-1-butanesulfonyl amine (NPBA), isophorone diisocyanate, and isophoronediamine. With the increase of NPBA content, the weight loss temperature, glass transition temperature, and tensile strength of FWPU-UA were all improved. Gaussian fitting analysis of infrared data and density functional theory simulation proved that the introduction of fluorine side chains increased the interaction of hydrogen bonding in the FWPU-UA. X-ray photoelectron spectroscopy analysis indicated that the aggregation of fluorine atoms on the surface of film were caused by the migration and enrichment of fluorine side chains. Furthermore, the water resistance of polyurethane-urea film could be significantly improved by adding a small amount of NPBA, and the seven-day water absorption rate of polyurethane-urea film was reduced from 30.13% to 12.55%. 相似文献
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在近些年的发展中,我国经济水平得到了一个显著的增长,经济的增长推动了城市化的发展进程,进入21世纪,城市绿化工程建设规模呈一个稳定上升的趋势,在这种大的社会环境形势下,如何做好绿化大管径供水管线的安装与腐蚀防护工作成为了行业关注的焦点。大管径供水管线的稳定性关系着城市发展的可持续性,要从多方面做好大管径供水管线的安装工作,采取有效的措施应对管线腐蚀问题。 相似文献
24.
介绍了采用变温吸附技术对氯乙烯进行干燥脱水的工艺流程及运行效果,阐述了变温吸附装置运行过程中出现的问题及相应的解决方法。 相似文献
25.
N. Clament Sagaya Selvam Lijie Du Bao Yu Xia Pil J. Yoo Bo You 《Advanced functional materials》2021,31(12):2008190
Electroreduction of small molecules such as H2O, CO2, and N2 for producing clean fuels or valuable chemicals provides a sustainable approach to meet the increasing global energy demands and to alleviate the concern on climate change resulting from fossil fuel consumption. On the path to implement this purpose, however, several scientific hurdles remain, one of which is the low energy efficiency due to the sluggish kinetics of the paired oxygen evolution reaction (OER). In response, it is highly desirable to synthesize high-performance and cost-effective OER electrocatalysts. Recent advances have witnessed surface reconstruction engineering as a salient tool to significantly improve the catalytic performance of OER electrocatalysts. In this review, recent progress on the reconstructed OER electrocatalysts and future opportunities are discussed. A brief introduction of the fundamentals of OER and the experimental approaches for generating and characterizing the reconstructed active sites in OER nanocatalysts are given first, followed by an expanded discussion of recent advances on the reconstructed OER electrocatalysts with improved activities, with a particular emphasis on understanding the correlation between surface dynamics and activities. Finally, a prospect for clean future energy communities harnessing surface reconstruction-promoted electrochemical water oxidation will be provided. 相似文献
26.
Yan He Kangren Kong Zhengxi Guo Weifeng Fang Zaiqiang Ma Haihua Pan Ruikang Tang Zhaoming Liu 《Advanced functional materials》2021,31(26):2101291
Sensitivity and multi-directional motivation are major two factors for developing optimized humidity-response materials, which are promising for sensing, energy production, etc. Organic functional groups are commonly used as the water sensitive units through hydrogen bond interactions with water molecules in actuators. The multi-coordination ability of inorganic ions implies that the inorganic ionic compounds are potentially superior water sensitive units. However, the particle forms of inorganic ionic compounds produced by classical nucleation limit the number of exposed ions to interact with water. Recent progress on the inorganic ionic oligomers has broken through the limitation of classical nucleation, and realized the molecular-scaled incorporation of inorganic ionic compounds into an organic matrix. Here, the incorporation of hydrophilic calcium carbonate ionic oligomers into hydrophobic poly(vinylidene fluoride) (PVDF) is demonstrated. The ultra-small calcium carbonate oligomers within a PVDF film endow it with an ultra-sensitive, reversible, and bidirectional response. The motivation ability is superior to other bidirectional humidity-actuators at present, which realizes self-motivation on an ice surface, converting the chemical potential energy of the humidity gradient from ice to kinetic energy. 相似文献
27.
Jin-Bo Pan Sheng Shen Lang Chen Chak-Tong Au Shuang-Feng Yin 《Advanced functional materials》2021,31(36):2104269
Photoelectrochemical (PEC) water splitting into hydrogen and oxygen is a promising solution for the conversion and storage of solar energy. Because sluggish water oxidation is the bottleneck of water splitting, the design and preparation of an efficient photoanode is intensively investigated. Currently, all known photoanode materials suffer from at least one of the following drawbacks: ① low carriers separation efficiency; ② sluggish surface water oxidation reaction; ③ poor long-term stability; ④ insufficient water adsorption and gas desorption. Core–shell configurations can endow a photoanode with improved activity and stability by coating an overlayer that plays energetic, catalytic, and/or protective roles. The construction strategy has an important effect on the activity of a core–shell photoanode. Nonetheless, the mechanism for the improvement of performance is still ambiguous and is worthy of a closer examination. In this review, the successes and challenges of core–shell photoanodes for water oxidation, focusing on synthesis strategies as well as functionalities (facilitating carrier separation, surface reaction promotion, corrosion prevention, and bubble detachment) are explored. Finally, the perspectives of this class of materials in terms of new opportunities and efforts are discussed. 相似文献
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给水管道在使用过程中很容易受到人为外力、管道材质、地下水、周围空气、土壤等因素的影响而腐蚀,影响了管道的使用质量和寿命,也带来较大的安全隐患。本文主要是从给水管道腐蚀原因出发,并探讨防护措施。 相似文献
30.
归一化水体指数(NDWI)是水体遥感反演的一种重要指标,其阈值及修正直接影响反演结果的精度。基于Landsat-8与GF-1光学多光谱影像,使用归一化水体指数法阈值0(TH0)、最大类间方差法(OTSU)自适应阈值(THotsu)与均值漂移聚类算法(Mean-Shift)自适应阈值(THMS)分别对典型正常水体、云雾覆盖水体、富营养化水体、高含泥沙水体进行水体遥感提取与效果分析,结果表明:正常水体以TH0为阈值提取精度最高,THMS提取精度次之,THotsu提取精度最差;而云雾覆盖水体、富营养化水体以及含泥沙水体使用THMS提取精度最高,尤其少量云雾覆盖下的水体,THMS具有更明显的优势,TH0提取精度次之,THotsu提取精度最差;对于不同的阈值,Land?sat-8比GF-1总体表现出更高的水体提取精度。Mean-Shift算法应用于NDWI阈值修正与水体遥感反演具有快速、水质适应性强、效果稳定的优势,对尤其是复杂条件下的水体信息遥感反演具有较好的提取效果。 相似文献